when you install a 2008 DC you are changing the schema at that time, but you won't be breaking anything...the existing 2003 DCs can exist until you move the roles off of them and demote them (whenever you're ready). This is because you won't be running AD in 2008 mode yet. Once you're running only 2008 DCs then you can choose to raise the domain functional level to 2008 and you'll see more new features.
here's a good doc on functional levels and different versions of DCs....
http://www.petri.co.il/understanding-windows-server-2008-active-directory-domain-and-forest-functional-levels.htm