Here have lot of tutorial about VS 2010 (i.e. .NET 4.0)
http://www.appdev.com/visualstudio2010.aspFor entity framework, there is no special tutorial, but it is a part of C# 4.0 and VB.NET 4.0 tutorial. Its has a 30 minuts video on Entiry Framework and 30 min video on LINQ to Entities.
Below is link:
http://www.appdev.com/prodfamily.asp?catalog%5Fname=AppDevCatalog&category%5Fname=XXCProduct