a couple of options
1) Break the mirror and make sure you can still boot.
2) remove the 2nd 73 GB drive and replace with a 146 GB drive
use Imaging software to copy the 73 GB to the 146 GB
remove the 73 GB and replace it with the 146 GB.
Make sure you can boot.
add a 2nd 146 GB, and tell the controller to create the RAID from the first drive to the second ( make sure your controller can do this since otherwise it may wipe the drives.
other option.
remove both 73 GB drives
put in 2x 146 GB drives
create RAID 1
Use Ghost or imaging software to copy from the first 73 GB to the RAID 1 pair.
You will need to test that whatever cloning software you choose can support your Hard drive RAID controller
I hope this helps !