It wasn't meant to be condescending and snarky, but I do see why it would come across that way therefore I apologise for the wording.
Bottom line however is that no setting in Windows affects anything during the power off state after a shutdown. You do have the system BIOS, but there is also a BIOS in the network card. With Intel, while booting up look for the Intel Boot Agent message to show up shortly after turning on your computer. Try CTRL-S to access it's BIOS settings at that time.