Hi Brewersewer,
I can't reccomend moving to Exchange 2003 or 2007 enough in that the migration to 2003 involves about the same e amount of work for mailbox moves to a new 2000 server and doing so would mean you only need one 2003 server as your limit on standard edition would be 75GB for the info store. If your systems meet the requirements for a 2003 upgrade, I would reccomend going that route.
To answer the above questions:
1. Yes, you can do an offline degfrag and it will only affect mailboxes on the server that has a DB that is being defragged in that they will be offiline while the defrag is performed. You will not need to defrag boxes on the target mailbox server as there will be no whitespace to reclaim in the database immediately after mbox moves.
2. The store does not increase in size on the source mailbox server so you should not have to use the temp limit increase.
3. The mbox moves will use extra log file space as the boxes are moved but this does not count against the size of the database. If you're moving 8GB of mailboxes, make sure you have at least that amount of extra space on the drive that your log file resides.
Also, don't be surprised if you move 8GB of mailboxes to the new server but find that it freed up less than 8GB due to single instance storage being broken. See below.
http://support.microsoft.com/kb/175481Again, if you're looking to get out of a bind and don't have the time to do a 2007 migration, a 2003 migration is really a good option in that you will do the same amount of work once and totally avoid the space issue altogether.