route add -p 10.0.0.0 mask 255.0.0.0 10.100.25.1 metric 1
It needs to go out via the gateway, your gateway is .1
http://support.microsoft.com/kb/140859The mask of all 255s (all 1s) means that the destination address of the packet to be routed must exactly match the Network Address for this route to be used. It has no mask.