Cannot go beyond 256 gb on a datastore which was created using the block size 1. See the following link for clarification.
http://itknowledgeexchange.techtarget.com/virtualization-pro/choosing-a-block-size-when-creating-vmfs-datastores/There is no way you can increase the block size without destroying the datastore. Just move all the files to another datastore using svMotion and reconfigure the datastore with what ever block size u feel is appropriate for furture use.