You will be fine migrating to a 2008R2 DC. Exchange 2007 cannot be installed on 2008 R2, but since you have a pre-existing installation, you have nothing to worry about other than making sure you do the transition of DC's correctly which you already have mapped out. I wouldn't immediately DCPromo the old server though, I would simply power it down and validate everything is functioning correctly then you may remove it completely after that.
Thanks