It is most likely that your user sign onto the web application hosted on an application server (or web server). The web server logs onto the database as some generic application user. This makes it difficult to simply query the database for specific wb application user.
A possible way of finding this information is to query for the context user. Both I believe you'll need to create a procedure to capture this information as a logon trigger. There is Fine-Grained Auditing method.
R.