The back button in most browsers bring you back to a cached page, controlled and maintained by the browser.
On the page you want to "expire", try adding the following at the top of the page;
1. Response.Buffer = True
2. Response.ExpiresAbsolute = Now().Subtract(New TimeSpan(1, 0, 0, 0))
3. Response.Expires = 0
4. Response.CacheControl = "no-cache"
This should prevent the browser from caching the page, thus preventing the user from viewing the page by going back.