Can you post a mdb/accdb with just the one table?
I tried it in Access 2007, but I suspect it works in 2003 as well. I had numbers and null fitting each of the 4 switch cases.
Try just this [verbatim] - the Switch for null test (first one below) must appear before all others.
SWITCH(
a.Assessment_Score&"" = "", "99999",
a.Assessment_Score > 36, "88888",
a.Assessment_Score < 0, "88888",
True, a.Assessment_Score
) AS T_Assessment_Score
FROM T_ASSESMENT_MONITORING AS a, T100_MON_CAT_DOC AS c
WHERE a.Assessment_period='2010 Term 3'
And a.Assessment_Category='101'
And a.Form='4/5 M'
And a.Assessment_Category_Doc=c.Category_Document_Description;