The memory you are using must be x4 or x8 based DIMMS for Advanced ECC
Optimized - uses all the memory channels to use all the memory and will produce the best performance
Advanced ECC- will pair up memory channels on each processor and are required to be in specific slots on the MB (I think the slots with the white tabs) I think you will need two more 2GB (one for each processor) to get Advanced ECC to work.