There are two things which I can think of:
1. The email client/server which sends the email encodes the PDF file as a MIME type; now for some reason when they are sending this particular file they are associating MIME as file/pdf rather than application/pdf. And as WG SMTP proxy is only configured to allow application/pdf it raised an alarm.
2. Other than sender, there is a piece of code [read SMTP proxy] which understands the incoming data and then decides what MIME type it is; for some reason [uknown to me, might be a code bug] WG SMTP proxy understands that the incoming attachment is file/pdf rather than application/pdf.
Thank you.