Yes, you should be able to use Wireshark to inspect the "GET" packet for the http request.
You can also use NetMon from microsoft.
Alternate solution:
You can also use NetCat, to listen on port 80 so you can visually see the entire packet in plain text.
nc.exe -l -p 80
Then on a test machine...get to the point where you want to send the request, and you then temporarily edit your HOSTS file to point the request to your machine.
domain.com 127.0.0.1